THIS IS WHAT HAPPENS INSIDE A BATTERY RIGHT BEFORE IT EXPLODES OVERCHARGED BATTERIES TURN INTO DEFORMED JELLYROLLS By Sarah Fecht
Overworking or overcharging a lithium-ion battery can cause deformation in its spiral-shaped electrode.
From the fiery Note 7 debacles to exploding hoverboards, lithium-ion batteries aren’t doing so hot lately. A new study helps to explain how these popular power sources can turn into safety hazards.
In the paper, published in the Journal of the Electrochemical Society, scientists at the Canadian Light Source (CLS) synchrotron looked inside an overworked battery. In this case, they drained a battery until its voltage was below a critical level.
Overcharging or overworking deforms the insides of a battery. (A) shows the inside of a battery before it was misused. (B) shows how misuse causes the original design defects to become even more warped. © highlights the areas where warping got worse.
When we overcharge or overheat lithium ion batteries, the materials inside start to break down and produce bubbles of oxygen, carbon dioxide, and other gases. Pressure builds up, and the hot battery swells from a rectangle into a pillow shape. Sometimes the phone involved will operate afterwards. Other times it will die. And occasionally—kapow!
To see what’s happening inside the battery when it swells, the CLS team used an x-ray technique called computed tomography.
Inside the battery is an electrode that spirals out from a central point like a jellyroll. The x-ray scan revealed that the bubbles produced during overheating warped and dented this electrode.
Intriguingly, the study authors found that the worst deformation from the gas buildup occurred in areas that had slight defects before the battery was ever over-drained. The authors note that doing more studies like this, on a larger variety of batteries, would improve understanding of how these batteries respond to gas evolution, which could lead to better designs.